TiO2-SnO2 Composites and Solid Solutions for Chemical Nanosensors

NANOSENSORS ENGINEERING: I. STRUCTURALLY MODULATED SnO2 NANOWIRES

The results of research aimed at the gas sensing nanowires (NWs) engineering are presented. Structurally modulated SnO2 NWs were obtained at 900С in the modified vapor-solid process, allowing that NW morphology could be encoded in a programmable way along its length. PVD technique was used for Ti/Au electrical contacts deposition and gas sensitive nanoscale chemiresistors formation. Created nan...

First principles analysis of H2O adsorption on the (110) surfaces of SnO2, TiO2 and their solid solutions.

Both associative and dissociative H(2)O adsorption on SnO(2)(110), TiO(2)(110), and Ti-enriched Sn(1-x)Ti(x)O(2)(110) surfaces have been investigated at low ((1)/(12) monolayer (ML)) and high coverage (1 ML) by density functional theory calculations using the Gaussian and plane waves formalism. The use of a large supercell allowed the simulation at low symmetry levels. On SnO(2)(110), dissociat...

Nanocrystalline TiO2/SnO2 heterostructures for gas sensing

The aim of this research is to study the role of nanocrystalline TiO2/SnO2 n-n heterojunctions for hydrogen sensing. Nanopowders of pure SnO2, 90 mol % SnO2/10 mol % TiO2, 10 mol % SnO2/90 mol % TiO2 and pure TiO2 have been obtained using flame spray synthesis (FSS). The samples have been characterized by BET, XRD, SEM, HR-TEM, Mössbauer effect and impedance spectroscopy. Gas-sensing experiment...

Structure design and photocatalytic properties of one-dimensional SnO2-TiO2 composites

One-dimensional SnO2-TiO2 composites were prepared via emulsion electrospinning process. The obtained samples were characterized by a series of devices. The results showed that the porous core-shell SnO2-TiO2 photocatalyst exhibited enhanced photocatalytic activity on the degradation of methyl orange (MO). It should be ascribed to the novel structure, which could separate the electrons and hole...

Electrospun TiO2/SnO2 Nanofibers with Innovative Structure and Chemical Properties for Highly Efficient Photocatalytic H2 Generation